Fluorous triphase and other multiphase systems
作者： Hiroyuki Nakamura , Lifang Sun , Stephen G. Weber , Dennis P. Curran , Bruno Linclau
DOI:
关键词:
摘要: A method of reacting a first compound to produce second includes the step contacting non-fluorous phase including with fluorous at interface. The distributes between and phase. further steps interface least third in that reacts compound. has distribution coefficient less than This can, for example be used separate from unreacted wherein, example, is nature more readily into (or transports quickly through) does In general, serves as barrier prevent two phases mixing, but molecules can migrate through pass one side other.
lens.org 参考文章(16)
Armido Studer, Dennis P. Curran, Sabine Hadida, Masahide Hoshino, Fluorous reaction systems ,(1996)
Louis B. Hoff, Shaheer H. Khan, Roger A. O'Neill, Method and apparatus for automated carbohydrate mapping and sequencing ,(1995)
Rafael Ferritto, Peter Wipf, Patrick Jeger, Armido Studer, Dennis P. Curran, Sun-Young Kim, Masahide Hoshino, Sabine Hadida Ruah, Fluorous reaction and separation systems ,(1996)
Alexander N. Glazer, Scott C. Benson, DNA complexes with dyes designed for energy transfer as fluorescent markers ,(1993)
M. Cavazzini, F. Montanari, G. Pozzi, S. Quici, Perfluorocarbon-soluble catalysts and reagents and the application of FBS (fluorous biphase system) to organic synthesis Journal of Fluorine Chemistry. ,vol. 94, pp. 183- 193 ,(1999) , 10.1016/S0022-1139(98)00358-3
Richard H. Fish, Fluorous Biphasic Catalysis: A New Paradigm for the Separation of Homogeneous Catalysts from Their Reaction Substrates and Products Chemistry - A European Journal. ,vol. 5, pp. 1677- 1680 ,(1999) , 10.1002/(SICI)1521-3765(19990604)5:6<1677::AID-CHEM1677>3.0.CO;2-X
István T. Horváth, Fluorous Biphase Chemistry Accounts of Chemical Research. ,vol. 31, pp. 641- 650 ,(1998) , 10.1021/AR970342I
Eric G Hope, Alison M Stuart, Fluorous biphase catalysis web science. ,vol. 100, pp. 75- 83 ,(1999) , 10.1016/S0022-1139(99)00204-3
Dennis P. Curran, Strategy-Level Separations in Organic Synthesis: From Planning to Practice Angewandte Chemie International Edition. ,vol. 37, pp. 1174- 1196 ,(1998) , 10.1002/(SICI)1521-3773(19980518)37:9<1174::AID-ANIE1174>3.0.CO;2-P
Elwin de Wolf, Gerard van Koten, Berth-Jan Deelman, Fluorous phase separation techniques in catalysis Chemical Society Reviews. ,vol. 28, pp. 37- 41 ,(1999) , 10.1039/A805644G