Ion Imaging Studies of Chemical Dynamics

作者: D. W. Chandler , J. R. Barker , A. J. R. Heck , M. H. M. Janssen , K. T. Lorenz

DOI: 10.1007/978-3-642-56800-8_34

关键词: PhotodissociationChemical physicsIntramolecular forceIonChemical DynamicsChemical reactionIntermolecular forceMaterials scienceScatteringInelastic scattering

摘要: Chemical dynamics is the exacting study of individual details chemical reactions. This involves studying both intramolecular and intermolecular motion energy mass. A new tool in ion imaging. Unimolecular photodissociation [1, 2, 3], reactive scattering [4, 5] inelastic [6, 7] are areas that have been investigated over last several years using Many these experiments were performed at Dynamics Visitors Laboratory Sandia National Laboratories. Two-dimensional imaging techniques allow measurement velocity a state-selectively photoionized product unimolecular dissociation or bimolecular interaction. In few there significant improvements with further development mapping accelerated application to this paper we present an overview some highlight experimental capabilities available.

参考文章(18)
David W. Neyer, Albert J. R. Heck, David W. Chandler, Photodissociation of N2O: J-dependent anisotropy revealed in N2 photofragment images Journal of Chemical Physics. ,vol. 110, pp. 3411- 3417 ,(1999) , 10.1063/1.478207
Theofanis N Kitsopoulos, Mark A Buntine, David P Baldwin, Richard N Zare, David W Chandler, None, Reaction Product Imaging: The H + D2 Reaction Science. ,vol. 260, pp. 1605- 1610 ,(1993) , 10.1126/SCIENCE.260.5114.1605
André T. J. B. Eppink, David H. Parker, Methyl iodide A-band decomposition study by photofragment velocity imaging Journal of Chemical Physics. ,vol. 109, pp. 4758- 4767 ,(1998) , 10.1063/1.477087
David W. Chandler, David W. Neyer, Albert J. R. Heck, High-resolution photoelectron images and D+photofragment images following 532-nm photolysis of D 2 Laser Techniques for State-Selected and State-to-State Chemistry IV. ,vol. 3271, pp. 104- 113 ,(1998) , 10.1117/12.308400
L. Schnieder, K. Seekamp-Rahn, E. Wrede, K. H. Welge, Experimental determination of quantum state resolved differential cross sections for the hydrogen exchange reaction H+D2→HD+D Journal of Chemical Physics. ,vol. 107, pp. 6175- 6195 ,(1997) , 10.1063/1.474283
Alice E. Thornley, Jeremy M. Hutson, The intermolecular potential of Ar-acetylene. Information from infrared and microwave spectroscopy Chemical Physics Letters. ,vol. 198, pp. 1- 8 ,(1992) , 10.1016/0009-2614(92)90039-P
Toshinori Suzuki, Hideki Katayanagi, Yuxiang Mo, Kenichi Tonokura, Evidence for multiple dissociation components and orbital alignment in 205 nm photodissociation of N2O Chemical Physics Letters. ,vol. 256, pp. 90- 95 ,(1996) , 10.1016/0009-2614(96)00429-0
A. G. Suits, L. S. Bontuyan, P. L. Houston, B. J. Whitaker, Differential cross sections for state-selected products by direct imaging : Ar+NO Journal of Chemical Physics. ,vol. 96, pp. 8618- 8620 ,(1992) , 10.1063/1.462265
David W. Chandler, Paul L. Houston, Two‐dimensional imaging of state‐selected photodissociation products detected by multiphoton ionization The Journal of Chemical Physics. ,vol. 87, pp. 1445- 1447 ,(1987) , 10.1063/1.453276
Laurie M. Yoder, John R. Barker, K.Thomas Lorenz, David W. Chandler, Ion imaging the recoil energy distribution following vibrational predissociation of triplet state pyrazine–Ar van der Waals clusters Chemical Physics Letters. ,vol. 302, pp. 602- 608 ,(1999) , 10.1016/S0009-2614(99)00176-1