Thermal behavior and immersion heats of selected clays from Turkey

作者: Meryem Sakizci , Burcu Erdoğan Alver , Ertuğrul Yörükoğullari

DOI: 10.1007/S10973-009-0294-Y

关键词: MineralogyCalorimeterBentoniteDifferential scanning calorimetryMontmorilloniteThermal analysisSpecific surface areaMaterials scienceKaoliniteAnalytical chemistryQuartz

摘要: Four clays (two bentonites and two kaolinites) from Turkey were investigated by X-ray diffraction (XRD), thermal analysis (DTA/TG-DSC) surface area measurement techniques. Mineralogically bentonite samples characterized low concentration of montmorillonite high level impurities. Both kaolinite mainly contained quartz as major mineral. TG-DTA curves all clay measured in the temperature range 30–1200 °C. The total % weight losses for (B1 B2) (K1 K2) determined 14.50, 13.42, 5.55 11.85%, respectively. Differential Scanning Calorimeter (DSC) analyses carried out heating 30 to 550 immersion heats using with a Calvet-type C-80 calorimeter. higher exothermic Qimm values compared samples.

参考文章(57)
G. Norman White, Joe B. Dixon, Kaolin–Serpentine Minerals Soil Mineralogy with Environmental Applications. pp. 389- 414 ,(2018) , 10.2136/SSSABOOKSER7.C12
Mireille L. Harmelin-Vivien, La thermo-analyse Presses Universitaires de France. ,(1968)
D. G. Schulze, J. B. Dixon, Soil mineralogy with environmental applications. Soil mineralogy with environmental applications.. ,(2002)
J. Kristóf, R. L. Frost, E. Horváth, L. Kocsis, J. Inczédy, Thermoanalytical Investigations on Intercalated Kaolinites Journal of Thermal Analysis and Calorimetry. ,vol. 53, pp. 467- 475 ,(1998) , 10.1023/A:1010189324654
B. Velde, Introduction to clay minerals: chemistry, origins, uses and environmental significance. 1. MINERAL,Introduction to clay minerals : chemistry, origins, uses and environmental significance. ,vol. 1992, pp. 1- 99 ,(1992)
M. Palomba, R. Porcu, Thermal behaviour of some minerals Journal of Thermal Analysis and Calorimetry. ,vol. 34, pp. 711- 722 ,(1988) , 10.1007/BF02331773
V. Hlavatý, V. Š. Fajnor, Thermal Stability of Clay/organic Intercalation Complexes Journal of Thermal Analysis and Calorimetry. ,vol. 67, pp. 113- 118 ,(2002) , 10.1023/A:1013789931016
V. Balek, Z. Málek, S. Yariv, G. Matuschek, Characterization of Montmorillonite Saturated with Various Cations Journal of Thermal Analysis and Calorimetry. ,vol. 56, pp. 67- 76 ,(1999) , 10.1023/A:1010179207262
A. K. Chakraborty, NEW DATA ON THERMAL EFFECTS OF KAOLINITE IN THE HIGH TEMPERATURE REGION Journal of Thermal Analysis and Calorimetry. ,vol. 71, pp. 799- 808 ,(2003) , 10.1023/A:1023318008031
A. Haouzi, F. Salles, M. Henry, J.-M. Douillard, Thermodynamic analysis of the immersion of a smectite substituted with Na or Ca: heat effect due to the cation. joint international conference on information sciences. ,vol. 307, pp. 531- 542 ,(2007) , 10.1016/J.JCIS.2006.07.048