Metal-free NaI/TBHP-mediated sulfonylation of thiols with sulfonyl hydrazides.
作者： Qian Chen , Yulin Huang , Xiaofeng Wang , Jiawei Wu , Guodian Yu
DOI: 10.1039/C8OB00244D
关键词: Combinatorial chemistry 、 Chemistry 、 Metal free 、 Sulfonyl
摘要: A highly efficient sulfonylation of thiols has been achieved through the metal-free NaI/TBHP-mediated cross-coupling sulfonyl hydrazides and at room temperature. This method provides a convenient practical route to thiosulfonates in 84-99% yields (39 examples) with wide functional group compatibility.
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