Halogen bonding effects on the outcome of reactions at metal centres.
作者： Lucas Carreras , Jordi Benet-Buchholz , Antonio Franconetti , Antonio Frontera , Piet W. N. M. van Leeuwen
DOI: 10.1039/C8CC08884E
关键词: Rhodium 、 Halogen bond 、 Medicinal chemistry 、 Metal 、 Halogen 、 Oxidative addition 、 Chemistry 、 Ligand
摘要: Key findings regarding the effects of ligand preorganisation via halogen bonding on outcome reactions at rhodium are reported. An unprecedented bonding-mediated oxidative addition CAr-I bonds to with efficient formation cyclometallated species deserves special mention.
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