Hydrothermal synthesis method of nickel phosphide nanoparticles
作者： Bo Wang , Xiang Huang , Zhibin Zhu , He Huang , Jinhui Dai
DOI: 10.1007/S13204-012-0057-0
关键词: Nanochemistry 、 Materials science 、 Metallurgy 、 Nanoparticle 、 Nickel 、 Nuclear chemistry 、 Hydrothermal synthesis 、 Raw material 、 Hydrothermal circulation 、 Chloride 、 Phosphide
摘要: Nanometer nickel phosphide compounds (Ni2P and Ni12P5) were synthesized via a mild hydrothermal method with red phosphor chloride as raw materials. XRD, EDS, TEM SEM analysis employed to characterize the obtained products. The results showed that as-prepared products well crystallized particle sizes ranged from 10 40 nm. Effects of material ratios initial pH reaction system on final investigated. result increased P/Ni ratio benefited formation Ni2P but went against obtaining Ni12P5 nanoparticles only in alkaline environment.
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Jennifer Ann Aitken, Valentina Ganzha-Hazen, Stephanie L. Brock, Solvothermal syntheses of Cu3P via reactions of amorphous red phosphorus with a variety of copper sources Journal of Solid State Chemistry. ,vol. 178, pp. 970- 975 ,(2005) , 10.1016/J.JSSC.2004.10.004
He Huang, Xiang Huang, Zhibin Zhu, Jinhui Dai, Hydrothermal synthesis of cobalt phosphide nanoparticles Ceramics International. ,vol. 38, pp. 1713- 1715 ,(2012) , 10.1016/J.CERAMINT.2011.09.001
K. A. Gingerich, Vaporization Behavior and Phosphorus Decomposition Pressures of Tungsten Monophosphide The Journal of Physical Chemistry. ,vol. 68, pp. 768- 772 ,(1964) , 10.1021/J100786A009
Adrian T. Rowley, Ivan P. Parkin, Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide Journal of Materials Chemistry. ,vol. 3, pp. 689- 692 ,(1993) , 10.1039/JM9930300689
STIG RUNDQVIST, New Metal-rich Phosphides of Niobium, Tantalum and Tungsten Nature. ,vol. 211, pp. 847- 848 ,(1966) , 10.1038/211847A0
Xinjun Wang, Fuquan Wan, Youjun Gao, Juan Liu, Kai Jiang, Synthesis of high-quality Ni2P hollow sphere via a template-free surfactant-assisted solvothermal route Journal of Crystal Growth. ,vol. 310, pp. 2569- 2574 ,(2008) , 10.1016/J.JCRYSGRO.2008.01.014
J. Gopalakrishnan, Sonal Pandey, K. Kasthuri Rangan, Convenient route for the synthesis of transition-metal pnictides by direct reduction of phosphate, arsenate, and antimonate precursors Chemistry of Materials. ,vol. 9, pp. 2113- 2116 ,(1997) , 10.1021/CM970175G
Zongyi Liu, Xiang Huang, Zhibin Zhu, Jinhui Dai, A simple mild hydrothermal route for the synthesis of nickel phosphide powders Ceramics International. ,vol. 36, pp. 1155- 1158 ,(2010) , 10.1016/J.CERAMINT.2009.12.015
A. L. Patterson, The Scherrer Formula for X-Ray Particle Size Determination Physical Review. ,vol. 56, pp. 978- 982 ,(1939) , 10.1103/PHYSREV.56.978
E. L. Muetterties, J. C. Sauer, Catalytic properties of metal phosphides. Qualitative assay of catalytic properties. I. Journal of the American Chemical Society. ,vol. 96, pp. 3410- 3415 ,(1974) , 10.1021/JA00818A012