Dibenzo[a,e]cyclooctene: Multi‐gram Synthesis of a Bidentate Ligand

作者: Géraldine Franck , Marcel Brill , Günter Helmchen

DOI: 10.1002/0471264229.OS089.05

关键词: Waste disposalLithiumExothermic reactionMedicinal chemistryOrganic chemistryCarbon tetrachloridePotassiumCycloocteneChemistryTetrahydrofuran

摘要: 5,6.11,12-Tetrahydodibenzo[a,e]cyclooctene Tetrahydrofuran Lithium 5,6,11,12,17,18-Hexahydro-tribenzo[a,e,i] cyclododecene 5,11-Dibromo-5,6,11,12-tetrahydrodobenzo[a,e]-cyclooctene N-Bromosuccinimide Carbon tetrachloride Dibenz[A,e]cyclooctene Potassium tert-butoxide Keywords: Multi-gram synthesis; Bi-dentate ligand.Transition metals; Complexes; Exothermic formation; Safety; Waste disposal

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