Enantioselective Modular Synthesis of Cyclohexenones: Total Syntheses of (+)-Crypto- and (+)-Infectocaryone

作者： Géraldine Franck , Kerstin Brödner , Günter Helmchen

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摘要: A modular synthesis of cyclohexenones is described and applied to the first enantioselective total syntheses (+)-crypto- (+)-infectocaryone. Key steps in are an iridium-catalyzed allylic alkylation, nucleophilic allylation, ring-closing metathesis. On way (+)-cryptocaryone, a catch release strategy involving iodolactonization/elimination regioselective C-acylation were used.

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Enantioselective Modular Synthesis of Cyclohexenones: Total Syntheses of (+)-Crypto- and (+)-Infectocaryone

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Enantioselective Modular Synthesis of Cyclohexenones: Total Syntheses of (+)-Crypto- and (+)-Infectocaryone

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