Kinetics and properties in metallocene catalysed propene polymerisations
作者： E. Ochoteco , M. Vecino , M. Montes , J.C. de la Cal
DOI: 10.1016/S0009-2509(01)00085-9
关键词: Zirconium 、 Metallocene 、 Heterogeneous catalysis 、 Solution polymerization 、 Chemistry 、 Methylaluminoxane 、 Catalysis 、 Homogeneous catalysis 、 Physical chemistry 、 Propene 、 Organic chemistry
摘要: Abstract The kinetic behaviour of propene polymerisation in heptane using bis(cyclopentadienyl)zirconium dichloride/methylaluminoxane as catalyst system was studied. Propene polymerisations were performed both homogeneous and heterogeneous systems. rate measured by continuously monitoring the monomer consumption. effect process variables such temperature, pressure, Al/Zr ratio concentration on catalytic performance (activity polymer properties) investigated. experimental results systems compared, a model proposed to fit evolution activity at different ratios concentrations for system.
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