New catalysts for olefin polymerization : from elementary processes to the synthesis of polyolefins
作者： Dorothée Coevoet , Henri Cramail , Alain Deffieux , Caroline Mladenov , Jean-Noël Pedeutour
DOI: 10.1002/(SICI)1097-0126(199904)48:4<257::AID-PI99>3.0.CO;2-M
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摘要: A general investigation of the elementary reactions involved in activation processes zirconocene and Ni-based derivatives by methylaluminoxane (MAO) was performed through association polymerization kinetics spectroscopic catalytic system. This study demonstrates close correlation between activities changes UV/visible characteristic absorption bands transition metal derivative used as catalyst. Hex-1-ene chosen model monomer.
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