Synthesis, Characterization, and Crystal Structure of a Dicyanamide-Bridged Polymeric Nickel(II) Complex With 4-Chloro-2-[(3-dimethylaminopropylimino)methyl]phenol
作者： Jian-Ying Miao
DOI: 10.1080/15533174.2012.761232
关键词: Monoclinic crystal system 、 Schiff base 、 Dicyanamide 、 Stereochemistry 、 Ligand 、 Octahedron 、 Reactivity (chemistry) 、 Nickel 、 Crystallography 、 Crystal structure 、 Chemistry
摘要: A dicyanamide-bridged polymeric nickel(II) complex, [NiL(MeOH)(μ2-N(CN)2)]n, where L is the anionic form of Schiff base 4-chloro-2-[(3-dimethylaminopropylimino)methyl] phenol, was synthesized and characterized by elemental analysis, IR spectrum, single-crystal X-ray diffraction. The crystal complex crystallizes in monoclinic space group P21/c, with unit cell dimensions a = 9.860(1) A, b 20.234(2) c 18.601(2) β 103.127(2)°, V 3614.0(6) A3, Z 4, R 1 0.0368, wR 2 0.0702. Ni atom an octahedral coordination, two N atoms ligand, one methanol O atom, teminal dicynamide ligand defining equatorial plane, phenolate terminal another dicyanate occupying axial positions. Supplemental materials are available for this article. Go to publisher's online edition Synthesis Reactivity Inorganic, Metal-Organic, Nano-M...
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