Synthesis, Electrochemical Behaviors and Anion Recognition of A Novel Star-[Polystyrene-b-poly(ferrocenyloxy ethyl acrylate)]6 with Hexafunctional Cyclotriphosphazene Core
作者： Anguo Xiao , Zhijun Li , Shibiao Zhou , Qingyun Zheng , Youming Shen
DOI: 10.1080/03602559.2012.654575
关键词: Ion 、 Ethyl acrylate 、 Polystyrene 、 HEXA 、 Electrochemistry 、 Materials science 、 Atom-transfer radical-polymerization 、 Polymer chemistry 、 Core (manufacturing) 、 Radical polymerization
摘要: A novel star-[polystyrene-b-poly(ferrocenyloxy ethyl acryl ate)]6 with hexa- functional cyclotriphosphazene core (star-(PS-b-PFcEA)6) was synthesized by atom -transfer radical polymerization(ATRP) and its electrochemical behaviors anion recognition investigated through CV. The results indicated that increasing of molecular weight resulted in obvious decreasing reduction peak potential Epc, the oxidation Epa kept comparatively stable. Moreover, when titrating into polymer solution, Epc increased while reduced evidently, which suggested star-(PS-b-PFcEA)6 provided high capacity .
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