作者: Zhiyou Du , Adel F. Sarofim , John P. Longwell
DOI: 10.1021/EF00021A014
关键词: Desorption 、 Carbochemistry 、 Distribution (number theory) 、 Thermal desorption spectroscopy 、 Pyrolysis 、 Analytical chemistry 、 Activation energy 、 Chemistry 、 Gaussian 、 Soot
摘要: A desorption model has been developed to determine the activation energy distribution of surface oxygen complex in TPD (temperature-programmed desorption). This two major advantages: 1) can be calculated directly from measurable data; 2) is principle capable dealing with any temperature programs experiments. Experimental studies an uncatalyzed soot material three different have carried out and resulted same using present model. The obtained found approximately Gaussian