Gas-Phase Ethylene/Hexene Copolymerization with Metallocene Catalyst in a Laboratory-Scale Reactor

作者: Bo Kou , Kim B. McAuley , C. C. Hsu , David W. Bacon , K. Zhen Yao

DOI: 10.1021/IE049067B

关键词: EthylenePost-metallocene catalystCopolymerLaboratory scaleHexeneMaterials scienceOrganic chemistryGas phase

摘要: Gas-phase ethylene and hexene copolymerization using a silica-supported (n-BuCp)2ZrCl2 metallocene catalyst has been investigated in 2 L laboratory reactor. Replicate experimental runs were condu...

参考文章(25)
K. D. Hungenberg, J. Kerth, F. Langhauser, B. Marczinke, R. Schlund, Gas Phase Polymerization of α-Olefins with Ziegler — Natta and Metallocene Catalysts: a Comparison Springer Berlin Heidelberg. pp. 363- 386 ,(1995) , 10.1007/978-3-642-79136-9_20
Richard B. Darlington, Regression and Linear Models ,(1990)
C Jeff Harlan, Simon G Bott, Andrew R Barron, None, Three-Coordinate Aluminum Is Not a Prerequisite for Catalytic Activity in the Zirconocene-Alumoxane Polymerization of Ethylene Journal of the American Chemical Society. ,vol. 117, pp. 6465- 6474 ,(1995) , 10.1021/JA00129A008
Eric T. Hsieh, James C. Randall, Monomer sequence distributions in ethylene-1-hexene copolymers Macromolecules. ,vol. 15, pp. 1402- 1406 ,(1982) , 10.1021/MA00233A036
Kyung-Jun Chu, Joao B. P. Soares, Alexander Penlidis, Effect of experimental conditions on ethylene polymerization within-situ-supported metallocene catalyst Journal of Polymer Science Part A. ,vol. 38, pp. 1803- 1810 ,(2000) , 10.1002/(SICI)1099-0518(20000515)38:10<1803::AID-POLA650>3.0.CO;2-X
Kyung-Jun Chu, C. Li Pi Shan, Joao B. P. Soares, Alexander Penlidis, Copolymerization of ethylene and 1-hexene with in-situ supported Et[Ind]2ZrCl2 Macromolecular Chemistry and Physics. ,vol. 200, pp. 2372- 2376 ,(1999) , 10.1002/(SICI)1521-3935(19991001)200:10<2372::AID-MACP2372>3.0.CO;2-4
Bo Kou, Kim B. McAuley, C. C. Hsu, David W. Bacon, K. Zhen Yao, Mathematical Model and Parameter Estimation for Gas-Phase Ethylene Homopolymerization with Supported Metallocene Catalyst Industrial & Engineering Chemistry Research. ,vol. 44, pp. 2428- 2442 ,(2005) , 10.1021/IE048957O