Gas Phase Polymerization of α-Olefins with Ziegler — Natta and Metallocene Catalysts: a Comparison

作者: K. D. Hungenberg , J. Kerth , F. Langhauser , B. Marczinke , R. Schlund

DOI: 10.1007/978-3-642-79136-9_20

关键词:

摘要: During the four decades since early discovery of K. Ziegler and G. Natta, polypropylene has grown to be one largest volume plastic materials with still an enormous growth rate about 6–8% per year. This is result a lot research optimization work on catalysts processes done by several companies institutes.

参考文章(20)
Takefumi Yano, Tokuji Inoue, Shigeru Ikai, Yoshiyuki Kai, Masanori Tamura, Michimasa Shimizu, Two‐step polymerization of propene by magnesium supported catalysts Die Makromolekulare Chemie, Rapid Communications. ,vol. 7, pp. 491- 495 ,(1986) , 10.1002/MARC.1986.030070711
Karl Ziegler, E. Holzkamp, H. Breil, H. Martin, Das Mülheimer Normaldruck-Polyäthylen-Verfahren Angewandte Chemie. ,vol. 67, pp. 541- 547 ,(1955) , 10.1002/ANGE.19550671902
A. Guyot, L. Bijhm, T. Sasaki, F. Karol, I. Hattori, U. Zucchini, Panel discussion I Which industrial polymerization catalysts for the future Macromolecular Symposia. ,vol. 66, pp. 311- 328 ,(1993) , 10.1002/MASY.19930660127
H. J. Zimmermann, A. G. Hoechst, Structural analysis of random propylene-ethylene copolymers Journal of Macromolecular Science, Part B. ,vol. 32, pp. 141- 161 ,(1993) , 10.1080/00222349308215477
T. Simonazzi, G. Cecchin, S. Mazzullo, An outlook on progress in polypropylene-based polymer technology Progress in Polymer Science. ,vol. 16, pp. 303- 329 ,(1991) , 10.1016/0079-6700(91)90021-C
E. L. Muetterties, W. D. Phillips, LEWIS ACID CHARACTER OF TELLURIUM HEXAFLUORIDE Journal of the American Chemical Society. ,vol. 79, pp. 2975- 2975 ,(1957) , 10.1021/JA01568A082
Wataru Minoshima, James L. White, Joseph E. Spruiell, Experimental investigation of the influence of molecular weight distribution on the rheological properties of polypropylene melts Polymer Engineering and Science. ,vol. 20, pp. 1166- 1176 ,(1980) , 10.1002/PEN.760201710
Walter Spaleck, Martin Antberg, Jürgen Rohrmann, Andreas Winter, Bernd Bachmann, Paul Kiprof, Joachim Behm, Wolfgang A. Herrmann, Hochmolekulares Polypropylen durch maßgeschneiderte Zirconocenkatalysatoren Angewandte Chemie. ,vol. 104, pp. 1373- 1376 ,(1992) , 10.1002/ANGE.19921041014
James N. Hay, Use of model compounds to determine equilibrium melting points of polymers Journal of Polymer Science Part A. ,vol. 14, pp. 2845- 2852 ,(1976) , 10.1002/POL.1976.170141201