Selectivity of C–H Activation and Competition between C–H and C–F Bond Activation at Fluorocarbons
作者： Odile Eisenstein , Jessica Milani , Robin N. Perutz
DOI: 10.1021/ACS.CHEMREV.7B00163
关键词: Chemical bond 、 Double bond 、 Fluorine 、 Medicinal chemistry 、 Chemistry 、 Transition metal 、 Organic chemistry 、 Mechanical bond 、 Regioselectivity 、 Quadruple bond 、 Bond order
摘要: … C–H activation reactions of Ni(PEt 3 ) 2 (η 2 -phenanthrene) with tetrafluoropyridine; (40) the rearrangement of the hydride complex trans-[NiH(C 6 F 4 (CF 3 ))(iPr 2 Im) 2 ] via the η 2 -…
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