Nanoindentation in Crystal Engineering: Quantifying Mechanical Properties of Molecular Crystals
作者： Sunil Varughese , MSRN Kiran , Upadrasta Ramamurty , Gautam R Desiraju , None
关键词: Polymorphism (materials science) 、 Desolvation 、 Anisotropy 、 Molecular solid 、 Nanotechnology 、 Crystal engineering 、 Materials science 、 Nanoindentation 、 Crystallography 、 Crystal 、 Elastic modulus
摘要: Nanoindentation is a technique for measuring the elastic modulus and hardness of small amounts materials. This method, which has been used extensively characterizing metallic inorganic solids, now being applied to organic metalorganic crystals, also become relevant subject crystal engineering, concerned with design molecular solids desired properties functions. Through nanoindentation it possible correlate molecular-level such as packing, interaction characteristics, inherent anisotropy micro/macroscopic events desolvation, domain coexistence, layer migration, polymorphism, solid-state reactivity. Recent developments exciting opportunities in this area are highlighted Minireview.
core.ac.uk 
sci-hub.se 参考文章(98)
Philippe Perrier, Stephen R. Byrn, Influence of crystal packing on the solid-state desolvation of purine and pyrimidine hydrates: loss of water of crystallization from thymine monohydrate, cytosine monohydrate, 5-nitrouracil monohydrate, and 2'-deoxyadenosine monohydrate Journal of Organic Chemistry. ,vol. 14, pp. 4671- 4676 ,(1982) , 10.1021/JO00145A013
Michael E. Brown, Mark D. Hollingsworth, Stress-induced domain reorientation in urea inclusion compounds Nature. ,vol. 376, pp. 323- 327 ,(1995) , 10.1038/376323A0
Raghunath P. Rastogi, N. B. Singh, Solid-state reactivity of picric acid and substituted hydrocarbons The Journal of Physical Chemistry. ,vol. 72, pp. 4446- 4449 ,(1968) , 10.1021/J100859A013
Rasmus B. Godiksen, Zachary T. Trautt, Moneesh Upmanyu, Jakob Schiøtz, Dorte Juul Jensen, Søren Schmidt, Simulations of boundary migration during recrystallization using molecular dynamics Acta Materialia. ,vol. 55, pp. 6383- 6391 ,(2007) , 10.1016/J.ACTAMAT.2007.07.055
Kyle J. Ramos, Daniel E. Hooks, David F. Bahr, Direct observation of plasticity and quantitative hardness measurements in single crystal cyclotrimethylene trinitramine by nanoindentation Philosophical Magazine. ,vol. 89, pp. 2381- 2402 ,(2009) , 10.1080/14786430903120335
T. P. Shakhtshneider, V. V. Boldyrev, Phase Transformations in Sulfathiazole During Mechanical Activation Drug Development and Industrial Pharmacy. ,vol. 19, pp. 2055- 2067 ,(1993) , 10.3109/03639049309069341
Changquan (Calvin) Sun, David J. W. Grant, Improved tableting properties of p-hydroxybenzoic acid by water of crystallization: a molecular insight Pharmaceutical Research. ,vol. 21, pp. 382- 386 ,(2004) , 10.1023/B:PHAM.0000016272.81390.B4
Yukoh Sakata, Sumihiro Shiraishi, Kozo Takayama, Makoto Otsuka, Effect of pulverization and dehydration on the pharmaceutical properties of calcium lactate pentahydrate tablets. Colloids and Surfaces B: Biointerfaces. ,vol. 51, pp. 149- 156 ,(2006) , 10.1016/J.COLSURFB.2006.07.004
G. M. J. Schmidt, Photodimerization in the solid state Pure and Applied Chemistry. ,vol. 27, pp. 647- 678 ,(1971) , 10.1351/PAC197127040647
MSRN Kiran, Sunil Varughese, C Malla Reddy, U Ramamurty, Gautam R Desiraju, None, Mechanical anisotropy in crystalline saccharin: nanoindentation studies Crystal Growth & Design. ,vol. 10, pp. 4650- 4655 ,(2010) , 10.1021/CG1009362