Native defects in gallium arsenide grown by molecular beam epitaxy and metallorganic chemical vapour deposition: effects of irradiation

作者: A. Jorio , C. Carlone , N.L. Rowell , A. Houdayer , M. Parenteau

DOI: 10.1016/0921-5107(95)01333-4

关键词: Materials scienceOptoelectronicsMolecular beam epitaxyChemical vapor depositionMetalorganic vapour phase epitaxySiliconGalliumGallium arsenidePhotoluminescenceDoping

摘要: Abstract Gallium arsenide (GaAs), doped n with silicon nominally to 10 15 and 16 cm −3 , grown by molecular beam epitaxy (MBE) metallorganic chemical vapour deposition (MOCVD), was characterized photoluminescence (PL) spectroscopy. In MOCVD GaAs, we found the signature of arsenic antisite (As Ga ) at 0.702 eV, but in MBE GaAs gallium (Ga As 1.441 eV as well site (Si 1.483 eV. We used proton (0.6–10 MeV) irradiation increase number intrinsic defects. The fluence range 13 −2 for 14 GaAs. At low fluences, effect reduce PL intensity, which became 10% 11 12 Annealing samples 550 °C 30 min resulted total recovery intensity only a 70% even these fluences. vacancies (V appeared irradiated samples, higher, never samples. conclude that under rich conditions conditions. material is about ten times more resistant radiation than presence V this may limit optical output devices depending on electron-hole recombination. case as-grown Si lowers recombination efficiency.

参考文章(7)
Kevin K. Smith, Photoluminescence of semiconductor materials Thin Solid Films. ,vol. 84, pp. 171- 182 ,(1981) , 10.1016/0040-6090(81)90465-X
D.J. Ashen, P.J. Dean, D.T.J. Hurle, J.B. Mullin, A.M. White, P.D. Greene, The incorporation and characterisation of acceptors in epitaxial GaAs Journal of Physics and Chemistry of Solids. ,vol. 36, pp. 1041- 1053 ,(1975) , 10.1016/0022-3697(75)90043-8
Phil Won Yu, D. C. Reynolds, Photoluminescence identification of ∼77‐meV deep acceptor in GaAs Journal of Applied Physics. ,vol. 53, pp. 1263- 1265 ,(1982) , 10.1063/1.330584
M. K. Nissen, A. Villemaire, M. L. W. Thewalt, Photoluminescence studies of theEL2 defect in gallium arsenide under external perturbations Physical Review Letters. ,vol. 67, pp. 112- 115 ,(1991) , 10.1103/PHYSREVLETT.67.112
Anouar Jorio, Aiguo Wang, Martin Parenteau, Cosmo Carlone, Nelson L. Rowell, Shyam M. Khanna, Optical identification of the gallium vacancy in neutron-irradiated gallium arsenide. Physical Review B. ,vol. 50, pp. 1557- 1566 ,(1994) , 10.1103/PHYSREVB.50.1557
A. Jorio, M. Parenteau, M. Aubin, C. Carlone, S.M. Khanna, J.W. Gerdes, A mobility study of the radiation induced order effect in gallium arsenide IEEE Transactions on Nuclear Science. ,vol. 41, pp. 1937- 1944 ,(1994) , 10.1109/23.340527