Structural characterization of Nd-doped in silica host matrix prepared by wet chemical process
作者： Surender Duhan , Sunita Devi , M. Singh
DOI: 10.1016/S1002-0721(08)60196-9
关键词: Neodymium 、 Annealing (metallurgy) 、 Analytical chemistry 、 Mineralogy 、 Nanocrystalline material 、 Infrared spectroscopy 、 Scanning electron microscope 、 Fourier transform infrared spectroscopy 、 Sintering 、 Amorphous solid 、 Materials science
摘要: Abstract Silica host matrix containing neodymium which is potentially important for the formation of nanocrystalline metal oxides was prepared by solgel method, using tetra-ethoxysilane and Nd(NO 3 ) as precursor materials. The samples were changed from amorphous to nanocrystallites phase at sintered temperature 550 °C (4 h), 750 (8 h) 950 (12 h). thermally treated sample microstructures investigated X-ray diffraction (XRD), Fourier transformation infrared spectroscopy (FTIR), scanning electron microscopy (SEM). While a further increase annealing time resulted in cubic hexagonal Nd 2 O nanocrystallites. At constant sintering 12 h, showed sharper intense peaks. sizes characterized XRD with average size ∼46 nm.
elsevier.com
sci-hub.se 参考文章(22)
Hari Singh Nalwa, Handbook of nanostructured materials and nanotechnology : Academic Press. ,(2000)
S. Duhan, P. Aghamkar, Influence of Temperature and Time on Nd2O3-SiO2Composite Prepared by the Solgel Process Acta Physica Polonica A. ,vol. 113, pp. 1671- 1677 ,(2008) , 10.12693/APHYSPOLA.113.1671
Mirosław Zawadzki, Leszek Kępiński, Synthesis and characterization of neodymium oxide nanoparticles Journal of Alloys and Compounds. ,vol. 380, pp. 255- 259 ,(2004) , 10.1016/J.JALLCOM.2004.03.053
E. Pinel, P. Boutinaud, R. Mahiou, What makes the luminescence of Pr3+different in CaTiO3 and CaZrO3 ? Journal of Alloys and Compounds. ,vol. 380, pp. 225- 229 ,(2004) , 10.1016/J.JALLCOM.2004.03.048
R. Bazzi, M.A. Flores-Gonzalez, C. Louis, K. Lebbou, C. Dujardin, A. Brenier, W. Zhang, O. Tillement, E. Bernstein, P. Perriat, Synthesis and luminescent properties of sub-5-nm lanthanide oxides nanoparticles Journal of Luminescence. ,vol. 102, pp. 445- 450 ,(2003) , 10.1016/S0022-2313(02)00588-4
Wu Yang, Youli Qi, Yongjun Ma, Xien Li, Xiaojun Guo, Jinzhang Gao, Miao Chen, Synthesis of Nd2O3 nanopowders by sol–gel auto-combustion and their catalytic esterification activity Materials Chemistry and Physics. ,vol. 84, pp. 52- 57 ,(2004) , 10.1016/J.MATCHEMPHYS.2003.09.042
Haruhiko Ono, Tooru Katsumata, Interfacial reactions between thin rare-earth-metal oxide films and Si substrates Applied Physics Letters. ,vol. 78, pp. 1832- 1834 ,(2001) , 10.1063/1.1357445
Wenxiu Que, X. Hu, L. H. Gan, G. Roshan Deen, Preparation and Luminescence Properties of Neodymium(III) Oxide Nanocrystals Dispersed in Sol-gel Titania/ (γ-glycidoxypropyl)Trimethoxysilane Composite Thin Films Journal of Materials Research. ,vol. 17, pp. 1399- 1405 ,(2002) , 10.1557/JMR.2002.0208
Leszek Kępiński, Mirosław Zawadzki, Włodzimierz Miśta, None, Hydrothermal synthesis of precursors of neodymium oxide nanoparticles Solid State Sciences. ,vol. 6, pp. 1327- 1336 ,(2004) , 10.1016/J.SOLIDSTATESCIENCES.2004.07.003
C.J.R. Gonzalez-Oliver, P.F. James, H. Rawson, Silica and silica-titania glasses prepared by the sol-gel process Journal of Non-crystalline Solids. ,vol. 48, pp. 129- 152 ,(1982) , 10.1016/0022-3093(82)90251-4