Electric dipole intensity parameters for Pr3+ in LiYF4

作者: Michael F. Reid , F.S. Richardson

DOI: 10.1016/0022-2313(84)90249-7

关键词: Electric dipole transitionElectrostatic modelAtomic physicsIntensity (heat transfer)DipoleLanthanideChemistrySuperposition principle

摘要: Abstract Intensity data for transitions between the 4f 2 crystal-field levels of Pr 3+ in LiYF 4 are parameterized. The results consistent with an electrostatic model f-f electric dipole intensities which includes both static effects and dynamic ligand-polarization effects. They also superposition lanthanide-ligand interactions lanthanide compounds.

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