Indirect and direct catalytic asymmetric reductive amination of 2-tetralone
作者： Oleg Bondarev , Christian Bruneau
DOI: 10.1016/J.TETASY.2010.03.027
关键词: Enantiomeric excess 、 Organic chemistry 、 Enamine 、 Reductive amination 、 Amine gas treating 、 Catalysis 、 Enantioselective synthesis 、 Chemistry 、 2-Tetralone
摘要: Herein we report a one-pot catalytic asymmetric reductive amination of 2-tetralone. High-throughput screening small library chiral ligands allowed us to perform the enantioselective hydrogenation intermediate enamine with up 60% ee and reaction 47% enantiomeric excess desired amine.
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