Orientation of an Organic Anion and Second-Staging Structure in Layered Double-Hydroxide Intercalates
作者： Nobuo Iyi , Keiji Kurashima , Taketoshi Fujita
DOI: 10.1021/CM0105211
关键词: Perpendicular 、 Azobenzene 、 Inorganic chemistry 、 Organic anion 、 Derivative (chemistry) 、 Hydroxide 、 Layered double hydroxides 、 Stacking 、 Intercalation (chemistry) 、 Crystallography 、 Chemistry
摘要: Mg−Al layered double hydroxides (LDHs) intercalated with an anionic azobenzene derivative (AzAA) were prepared, and the arrangement of incorporated AzAA was investigated by varying starting AzAA/LDH ratios for two types LDHs different Mg/Al mole ratios, = 2.0 (LDH2) 3.0 (LDH3). The observed basal spacings complexes, 8 23−25 A, ascribed to horizontal (parallel layers) vertical (perpendicular orientations AzAA, respectively. In general, orientation low higher ratios. For LDH2 a large spacing 33 A intermediate that is, 0.5 0.75, which interpreted as alternate stacking interlayers (“1:1 ordered interstratification” or “second staging”). case LDH3 complexes having smaller layer-charge density, second staging not found wit...
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