Effect of silane treatment parameters on the silane layer formation and bonding to thermoplastic urethane

作者: Maija Hoikkanen , Mari Honkanen , Minnamari Vippola , Toivo Lepistö , Jyrki Vuorinen

DOI: 10.1016/J.PORGCOAT.2011.08.002

关键词: Materials scienceLayer (electronics)Composite materialAdhesionCoatingOxideBond strengthSilaneThermoplasticMicrostructure

摘要: Abstract Enhancing adhesion is of primary importance in preparation insert injection molded plastic–metal hybrids. Here, the combination coupling agent application parameters and steel oxide microstructure effects on thermoplastic urethane–stainless hybrids was studied. The stainless structure first modified by electrolytical polishing subsequent oxidation treatment, then coated with N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane (γ-AEAPS) prior to overmolding urethane. properties formed silane coatings ultimately were determined several microscopical methods, infrared spectroscopy mechanical testing. bond strength depended layer thickness. Also surface had a remarkable influence coating formation resulting hybrid strength.

参考文章(24)
M. A. Petrunin, L. B. Maksaeva, A. I. Marshakov, The Effect of Surface Siloxane Layers on the Penetration of Hydrogen into Iron Protection of Metals. ,vol. 37, pp. 120- 125 ,(2001) , 10.1023/A:1010313819287
EP. Plueddemann, Silane Coupling Agents ,(1982)
Edward M. Petrie, Handbook of Adhesives and Sealants ,(1999)
M Honkanen, M Vippola, T Lepistö, Characterisation of stainless steel surfaces – modified in air at 350°C Surface Engineering. ,vol. 27, pp. 325- 331 ,(2011) , 10.1179/174329409X397750
M.K Harun, S.B Lyon, J Marsh, A surface analytical study of functionalised mild steel for adhesion promotion of organic coatings Progress in Organic Coatings. ,vol. 46, pp. 21- 27 ,(2003) , 10.1016/S0300-9440(02)00165-0
Wei Yuan, Wim J. van Ooij, Characterization of Organofunctional Silane Films on Zinc Substrates joint international conference on information sciences. ,vol. 185, pp. 197- 209 ,(1997) , 10.1006/JCIS.1996.4604
I. De Graeve, E. Tourwé, M. Biesemans, R. Willem, H. Terryn, Silane solution stability and film morphology of water-based bis-1,2-(triethoxysilyl)ethane for thin-film deposition on aluminium Progress in Organic Coatings. ,vol. 63, pp. 38- 42 ,(2008) , 10.1016/J.PORGCOAT.2008.04.002
D. Susac, X. Sun, K.A.R. Mitchell, Adsorption of BTSE and γ-APS organosilanes on different microstructural regions of 2024-T3 aluminum alloy Applied Surface Science. ,vol. 207, pp. 3133- 3143 ,(2003) , 10.1016/S0169-4332(02)01237-0