X-Ray Photoemission Study of Dodecanethiolate-Passivated Ag Nanoparticles
作者： Akinori Tanaka , Yuitsu Takeda
DOI: 10.1143/JPSJ.73.1543
关键词: Passivation 、 X-ray photoelectron spectroscopy 、 Chemical bond 、 Spectral line 、 Crystallography 、 Electronic structure 、 Atomic physics 、 Highly oriented pyrolytic graphite 、 Particle size 、 Nanoparticle 、 Materials science
摘要: We have carried out the X-ray photoemission study of dodecanethiolate-(DT-) passivated Ag nanoparticles supported on highly oriented pyrolytic graphite (HOPG) substrates. From detailed line-shape analyses 3 d core-level spectra DT-passivated nanoparticles, it is found that consist two components. attribute these components to inner atoms and surface bonded dodecanethiolates. Furthermore, we investigated nanoparticle-diameter-dependent valence-band spectra. results, discuss electronic properties nanoparticles.
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