Fines deposition dynamics in gas–liquid trickle‐flow reactors

作者: Ion Iliuta , Faïçal Larachi , Bernard P. A. Grandjean

DOI: 10.1002/AIC.690490218

关键词: CokePorosityFlow (psychology)Porous mediumMineralogyChemistryViscosityDeposition (phase transition)Gas compressorFiltrationMechanics

摘要: Nonfilterable fines, such as incipient coke particles or fines naturally occurring in oil sands bitumen, are known to be responsible for the severe plugging during flow of (fine) solid–liquid suspensions cocurrent gas–liquid trickle-bed hydrotreating reactors. Accumulating porous medium causes pressure buildup, and thus dropoff hydrogen partial bed, overutilizing recycling compressors shortening reactor operating cycles. In this work, a 1-D transient two-fluid hydrodynamic model based on macroscopic volume-average form multiphase system transport equations is developed, analyzed, validated experimentally. The hypothesizes that occurs via deep-bed filtration mechanisms. It incorporates physical effects porosity effective specific surface-area changes due capture inertial phases, coupling between filter rate equation interfacial momentum exchange force terms. tested trickle-flow regime conditions mimicking process with spherical trilobe catalysts. To rationalize phenomena reactors, parametric studies carried out liquid velocity viscosity, gas density velocity, feed concentration, dynamics.

参考文章(27)
Richard M. Propp, Phillip Colella, William Y. Crutchfield, Marcus S. Day, A numerical model for trickle bed reactors Journal of Computational Physics. ,vol. 165, pp. 311- 333 ,(2000) , 10.1006/JCPH.2000.6604
Arturo Ortiz-Arroyo, Faïçal Larachi, Bernard P. A. Grandjean, Shantanu Roy, CFD modeling and simulation of clogging in packed beds with nonaqueous media Aiche Journal. ,vol. 48, pp. 1596- 1609 ,(2002) , 10.1002/AIC.690480803
J. P. Herzig, D. M. Leclerc, P. Le. Goff, Flow of Suspensions through Porous Media—Application to Deep Filtration Industrial & Engineering Chemistry. ,vol. 62, pp. 8- 35 ,(1970) , 10.1021/IE50725A003
Ion Iliuta, Bernard P.A Grandjean, Faı̈çal Larachi, New mechanistic film model for pressure drop and liquid holdup in trickle flow reactors Chemical Engineering Science. ,vol. 57, pp. 3359- 3371 ,(2002) , 10.1016/S0009-2509(02)00205-1
Murray R. Gray, Naras Srinivasan, Jacob H. Masliyah, Pressure buildup in gas-liquid flow through packed beds due to deposition of fine particles Canadian Journal of Chemical Engineering. ,vol. 80, pp. 346- 354 ,(2002) , 10.1002/CJCE.5450800302
Mostafa Fourar, Roland Lenormand, Faı̈çal Larachi, Extending the F-function concept to two-phase flow in trickle beds Chemical Engineering Science. ,vol. 56, pp. 5987- 5994 ,(2001) , 10.1016/S0009-2509(01)00209-3
Yumin. Liu, Jeffrey. Schwartz, Cullen L. Cavallaro, Catalytic dechlorination of polychlorinated biphenyls. Environmental Science & Technology. ,vol. 29, pp. 836- 840 ,(1995) , 10.1021/ES00003A036
Daylin. Liu, Philip R. Johnson, Menachem. Elimelech, Colloid Deposition Dynamics in Flow-Through Porous Media: Role of Electrolyte Concentration Environmental Science & Technology. ,vol. 29, pp. 2963- 2973 ,(1995) , 10.1021/ES00012A012
Sanyi Wang, Keng H. Chung, Jacob H. Masliyah, Murray R. Gray, Deposition of Fine Particles in Packed Beds at Hydrotreating Conditions: Role of Surface Chemistry Industrial & Engineering Chemistry Research. ,vol. 38, pp. 4878- 4888 ,(1999) , 10.1021/IE990257+
S. Vigneswaran, Ravi Kumar Tulachan, Mathematical modelling of transient behaviour of deep bed filtration Water Research. ,vol. 22, pp. 1093- 1100 ,(1988) , 10.1016/0043-1354(88)90003-6