Excess molar volumes of methyl tert-butyl ether with chloroalkanes at 30°C
作者： S. C. Sharma , I. M. Joshi , Jasbir Singh , Alka Gupta
DOI: 10.1007/BF00647024
关键词: Chemistry 、 Molar volume 、 Ether 、 Molar 、 Medicinal chemistry 、 Aliphatic compound 、 Organic chemistry 、 Methyl tert-butyl ether
摘要: Excess molar volumes are reported for binary mixtures of methyl tert-butyl ether with trichloromethane, tetrachloromethane, 1,2-dichloroethane, 1,1,2-trichloroethane, 1,1,2,2-tetrachloroethane, or 1,1,1,2,2-pentachloroethane at 30°C over the entire composition range mixtures. all found to be negative. A qualitative interpretation results in terms O−H−C and Cl−O interactions is presented. The Prigogine-Flory-Patterson theory has been used analyze results.
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