Electrogenerated chemiluminescence triggered by electroseparation of Ru(bpy)32+ across a supported liquid membrane
作者： Gastón A. Crespo , Günter Mistlberger , Eric Bakker
DOI: 10.1039/C1CC14822B
关键词: Tris 、 Analytical chemistry 、 Membrane 、 Chemiluminescence 、 Photochemistry 、 Chemistry 、 Ruthenium
摘要: We demonstrate here for the first time detection of electrogenerated chemiluminescence (ECL) upon selective, electrochemically triggered tris(2,2′-bipyridyl)ruthenium(II) (Ru(bpy)32+) transport across a supported liquid membrane doped with lipophilic cation-exchanger. This approach allows one to separate location ECL generation from sample compartment, thereby avoiding contamination compounds necessary ECL.
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