Synthesis of silver/polymer colloidal composites from surface-functional porous polymer microspheres

作者: Jin-Woong Kim , Jung-Eun Lee , Su-Jin Kim , Jong-Suk Lee , Jee-Hyun Ryu

DOI: 10.1016/J.POLYMER.2004.04.062

关键词: Composite numberMicroparticleMaterials scienceNanoparticlePolymerSilver nitrateEthylene glycolPhase (matter)Chemical engineeringColloidPolymer chemistry

摘要: Abstract This study presents a different colloidal silver (Ag)/polymer system where Ag nanoparticles are deposited uniformly onto surface-functional porous poly(ethylene glycol dimethacrylate-co-acrylonitrile) (poly(EGDMA-co-AN)) microspheres. The formation and morphology of the composite microspheres were characterized from electron microscopy X-ray diffraction analyses. significance present report is that owing to high affinity between nitrile group (CN) on large surface microspheres, having face-centered cubic phase incorporated evenly into deep pores with fine size distribution. In preservation test, Ag/poly(EGDMA-co-AN) obtained showed an excellent anti-bacterial performance, elucidating applicability for new preservative.

参考文章(24)
Stephan Förster, Thomas Plantenberg, From Self-Organizing Polymers to Nanohybrid and Biomaterials Angewandte Chemie International Edition. ,vol. 41, pp. 688- 714 ,(2002) , 10.1002/1521-3773(20020301)41:5<688::AID-ANIE688>3.0.CO;2-3
TC Flanagan, , A Pandit, Living artificial heart valve alternatives: a review European Cells & Materials. ,vol. 6, pp. 28- 45 ,(2003) , 10.22203/ECM.V006A04
P. Jiang, K. S. Hwang, D. M. Mittleman, J. F. Bertone, V. L. Colvin, Template-Directed Preparation of Macroporous Polymers with Oriented and Crystalline Arrays of Voids Journal of the American Chemical Society. ,vol. 121, pp. 11630- 11637 ,(1999) , 10.1021/JA9903476
Jin-Woong Kim, Jung-Eun Lee, Jee-Hyun Ryu, Jong-Suk Lee, Su-Jin Kim, Sang-Hoon Han, Ih-Seop Chang, Hak-Hee Kang, Kyung-Do Suh, Synthesis of metal/polymer colloidal composites by the tailored deposition of silver onto porous polymer microspheres Journal of Polymer Science Part A. ,vol. 42, pp. 2551- 2557 ,(2004) , 10.1002/POLA.20125
D.P. Dowling, K. Donnelly, M.L. McConnell, R. Eloy, M.N. Arnaud, Deposition of anti-bacterial silver coatings on polymeric substrates Thin Solid Films. ,vol. 398, pp. 602- 606 ,(2001) , 10.1016/S0040-6090(01)01326-8
M. Okubo, T. Yamashita, T. Suzuki, T. Shimizu, Production of micron-sized monodispersed composite polymer particles by seeded polymerization utilizing the dynamic swelling method Colloid and Polymer Science. ,vol. 275, pp. 288- 292 ,(1997) , 10.1007/S003960050083
Jung-Bae Jun, Jin-Woong Kim, Joon-Woo Lee, Kyung-Do Suh, Spherical polarization body: Synthesis of monodisperse micron-sized polyaniline composite particles Macromolecular Rapid Communications. ,vol. 22, pp. 937- 940 ,(2001) , 10.1002/1521-3927(20010801)22:12<937::AID-MARC937>3.0.CO;2-6
Huaitian Bu, Jianghua Rong, Zhenzhong Yang, Template Synthesis of Polyacrylonitrile‐Based Ordered Macroporous Materials and Their Derivatives Macromolecular Rapid Communications. ,vol. 23, pp. 460- 464 ,(2002) , 10.1002/1521-3927(20020501)23:8<460::AID-MARC460>3.0.CO;2-7