Structural Modifications and Electrochemical Behavior of Lithium-Inserted In16Fe8S32
作者： C. Pérez Vicente , C. Bousquet , A. Krämer , J.L. Tirado , J. Olivier-Fourcade
关键词: X-ray crystallography 、 Mössbauer spectroscopy 、 Electronic band structure 、 Delocalized electron 、 Spectroscopy 、 Rietveld refinement 、 Spinel 、 Analytical chemistry 、 Lithium 、 Crystallography 、 Chemistry
摘要: The authors have studied the structural modifications that occur during electrochemical insertion of lithium into spinel compound In{sub 16}Fe{sub 8}S{sub 32}. Studies by X-ray diffraction (Rietveld analysis) and Moessbauer spectroscopy lithiated products indicate some cation migration takes place process. spectra show no reduction Fe{sup 2+} insertion. variation isomer shift indicates an increase in covalency network. results absorption experiments absence a clear In{sup 3+} incorporation incoming electrons delocalized band structure. Analysis discharge curve shows presence two different domains. For first one there is small interaction between inserted ions. second repulsive decrease diffusion coefficient.
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sci-hub.se 参考文章(16)
Fast Ion Transport in Solids Springer Netherlands. ,(1993) , 10.1007/978-94-011-1916-0
Materials for Advanced Batteries NASA STI/Recon Technical Report A. ,vol. 82, pp. 18112- ,(1980) , 10.1007/978-1-4684-3851-2
J. Morales, J.L. Tirado, M.L. Elidrissi Moubtassim, J. Olivier-Fourcade, J.C. Jumas, Electrochemical lithium insertion into In16Sn4S32 and Cu4In20S32 spinel sulphides Journal of Alloys and Compounds. ,vol. 217, pp. 176- 180 ,(1995) , 10.1016/0925-8388(94)01309-6
A JAMES, B ELLIS, J GOODENOUGH, Lithium insertion into the normal thiospinel CuZr2S4 and the defect thiospinel Cu0.05Zr2S4 Solid State Ionics. ,vol. 27, pp. 45- 55 ,(1988) , 10.1016/0167-2738(88)90488-2
M PERNET, P STROBEL, B BONNET, P BORDET, Y CHABRE, Structural and electrochemical study of lithium insertion into γ-Fe2O3 Solid State Ionics. ,vol. 66, pp. 259- 265 ,(1993) , 10.1016/0167-2738(93)90415-Y
R. A. Young, A. Sakthivel, T. S. Moss, C. O. Paiva-Santos, DBWS-9411 – an upgrade of the DBWS*.* programs for Rietveld refinement with PC and mainframe computers Journal of Applied Crystallography. ,vol. 28, pp. 366- 367 ,(1995) , 10.1107/S0021889895002160
M. Eisenberg, The Sulfospinel‐Lithium Battery System: Initial Study of Three Sulfospinels Journal of The Electrochemical Society. ,vol. 127, pp. 2382- 2383 ,(1980) , 10.1149/1.2129435
Alexander Frank . Wells, Structural inorganic chemistry ,(1945)
C. Bousquet, A. Krämer, C. Pérez Vicente, J.L. Tirado, J. Olivier-Fourcade, J.C. Jumas, Structural and Local Environment Modifications in a Chemically Lithiated Iron Thiospinel Journal of Solid State Chemistry. ,vol. 134, pp. 238- 247 ,(1997) , 10.1006/JSSC.1997.7546
Manfred Womes, Josette Olivier-Fourcade, Jean-Claude Jumas, Frank Aubertin, Ulrich Gonser, Characterization of the single phase region with spinel structure in the ternary system In2S3FeSFeS2 Journal of Solid State Chemistry. ,vol. 97, pp. 249- 256 ,(1992) , 10.1016/0022-4596(92)90032-Q