作者: Goutham Kukkadapu , Kamal Kumar , Chih-Jen Sung , Marco Mehl , William J. Pitz
DOI: 10.1016/J.COMBUSTFLAME.2012.05.008
关键词: Autoignition temperature 、 Homogeneous charge compression ignition 、 Chemistry 、 Heptane 、 Surrogate model 、 Octane rating 、 Octane 、 Gasoline 、 Nuclear engineering 、 Ignition system
摘要: Abstract The use of gasoline in Homogeneous Charge Compression Ignition engines has propelled the need to better understand compression ignition processes for under engine-like conditions. In order quantify low-temperature heat release and provide fundamental validation data chemical kinetic models, it is imperative study autoignition phenomena well-controlled However, there a significant lack delay low temperature regime. Recognizing information at high pressures low-to-intermediate temperatures, this work aims fill void by conducting an experimental Rapid Machine (RCM) characterize response gasoline + air mixtures over wide range temperatures 20 40 bar with equivalence ratios ranging from 0.3 1.0. Results RCM experiments are also simulated using four-component surrogate model which includes n -heptane, iso -octane, toluene, 2-pentene. For conditions investigated, good agreement between model, terms first-stage total times as well comparison measured pressure traces, demonstrated. Kinetic analysis further conducted role different hydrocarbon classes present controlling autoignition.