CFD modeling of a UV-A LED baffled flat-plate photoreactor for environment applications: a mining wastewater case

作者: John Steven Devia-Orjuela , Luis Andrés Betancourt-Buitrago , Fiderman Machuca-Martinez

DOI: 10.1007/S11356-018-2431-2

关键词: Potassium persulfateWastewaterUltraviolet lightLight-emitting diodeChemical engineeringSewage treatmentPotassium ferrioxalatePhotodegradationActinometerMaterials science

摘要: The use of ultraviolet light in photoreactors for wastewater treatment has become popular as an alternative known chemical oxidative substances. UV LED represents cheaper, robust, and versatile to traditional lamps. In this study, it was designed evaluated a photoreactor with approach fluid dynamics (CFD) experimental validation. evaluation consisted (1) CFD velocity profile analysis, (2) characterization the average distribution potassium ferrioxalate actinometry, (3) degradation typical recalcitrant metallic cyanocomplex Fe(CN)63−, (4) scavenger effect analysis photodegradation using persulfate. Actinometrical essay concluded that system able receive 1.93 μE/s. reactor operated under turbulent regime best result Fe(CN)63− obtained at 4 h operation, 5-W UV-A LEDs, pH ~ 7 10 mM de S2O82−. Baffled demonstrated be useful type illumination treatment.

参考文章(65)
Cathy McCullagh, Nathan Skillen, Morgan Adams, Peter K.J. Robertson, Photocatalytic reactors for environmental remediation: A review Journal of Chemical Technology & Biotechnology. ,vol. 86, pp. 1002- 1017 ,(2011) , 10.1002/JCTB.2650
A. Brucato, A. E. Cassano, F. Grisafi, G. Montante, L. Rizzuti, G. Vella, Estimating radiant fields in flat heterogeneous photoreactors by the six‐flux model Aiche Journal. ,vol. 52, pp. 3882- 3890 ,(2006) , 10.1002/AIC.10984
Saud Al-Omani, Fahdah Alokaily, SMJ changes and development Saudi Medical Journal. ,vol. 33, pp. 3- 4 ,(2012)
Leonor C. Ferreira, Marco S. Lucas, José R. Fernandes, Pedro B. Tavares, Photocatalytic oxidation of Reactive Black 5 with UV-A LEDs Journal of environmental chemical engineering. ,vol. 4, pp. 109- 114 ,(2016) , 10.1016/J.JECE.2015.10.042
Rafael van Grieken, José Aguado, María-José López-Muñoz, Javier Marugán, Photocatalytic degradation of iron–cyanocomplexes by TiO2 based catalysts Applied Catalysis B-environmental. ,vol. 55, pp. 201- 211 ,(2005) , 10.1016/J.APCATB.2004.08.008
Javier Marugán, Rafael van Grieken, Cristina Pablos, M. Lucila Satuf, Alberto E. Cassano, Orlando M. Alfano, Kinetic modelling of Escherichia coli inactivation in a photocatalytic wall reactor Catalysis Today. ,vol. 240, pp. 9- 15 ,(2015) , 10.1016/J.CATTOD.2014.03.005
Leandro G. Jeifetz, Pablo Daniel Giunta, Fernando J. Mariño, Norma E. Amadeo, Miguel Á. Laborde, Simulation of CO Preferential Oxidation (COPrOx) Monolithic Reactors International Journal of Chemical Reactor Engineering. ,vol. 12, pp. 1- 12 ,(2014) , 10.1515/IJCRE-2013-0071
Wan-Kuen Jo, Rajesh J. Tayade, New Generation Energy-Efficient Light Source for Photocatalysis: LEDs for Environmental Applications Industrial & Engineering Chemistry Research. ,vol. 53, pp. 2073- 2084 ,(2014) , 10.1021/IE404176G
Lucía d. C. Cid, María d. C. Grande, Eduardo O. Acosta, Berta Ginzberg, Removal of Cr(VI) and Humic Acid by Heterogeneous Photocatalysis in a Laboratory Reactor and a Pilot Reactor Industrial & Engineering Chemistry Research. ,vol. 51, pp. 9468- 9474 ,(2012) , 10.1021/IE2010687
Giovanni Palmisano, Vittorio Loddo, Vincenzo Augugliaro, Two-dimensional modeling of an externally irradiated slurry photoreactor International Journal of Chemical Reactor Engineering. ,vol. 11, pp. 675- 685 ,(2013) , 10.1515/IJCRE-2012-0049