Determination of the triplet state lifetime of vibrationally excited C60
作者： M. Hedén , A. V. Bulgakov , K. Mehlig , E. E. B. Campbell
DOI: 10.1063/1.1568730
关键词: Atomic physics 、 Triplet state 、 Pulse (physics) 、 Extrapolation 、 Photoexcitation 、 Photon 、 Ionization 、 Chemistry 、 Excited state 、 Fullerene
摘要: The lifetime of the ground triplet state vibrationally excited C60 has been determined in a two-color pump–probe experiment. An intense pump pulse (337 nm, 4 ns) was used to excite neutral molecules. probed via single photon ionization with weak probe (193 nm). found be on order 1 μs. This is rather low explain recent delayed results but higher than expected from an extrapolation earlier measurements at lower temperatures.
scitation.org
harvard.edu
aip.org
sci-hub.se 参考文章(14)
M. R. Fraelich, R. B. Weisman, Triplet states of fullerene C60 and C70 in solution: long intrinsic lifetimes and energy pooling The Journal of Physical Chemistry. ,vol. 97, pp. 11145- 11147 ,(1993) , 10.1021/J100145A002
F. Rohmund, M. Hedén, A. V. Bulgakov, E. E. B. Campbell, Delayed ionization of C60: The competition between ionization and fragmentation revisited The Journal of Chemical Physics. ,vol. 115, pp. 3068- 3073 ,(2001) , 10.1063/1.1385554
H. Thomas Etheridge, R. D. Averitt, N. J. Halas, R. Bruce Weisman, C60 TRIPLET LIFETIMES : VIBRATIONAL ENERGY DEPENDENCE FROM 0 TO 80 000 CM-1 The Journal of Physical Chemistry. ,vol. 99, pp. 11306- 11308 ,(1995) , 10.1021/J100029A003
A. Nitzan, J. Jortner, P.M. Rentzepis, Peculiarities of the non-radiative decay of a single vibronic level in polyatomic molecules Chemical Physics Letters. ,vol. 8, pp. 445- 447 ,(1971) , 10.1016/0009-2614(71)80424-4
K. Hansen, O. Echt, Thermionic Emission and Fragmentation of C 60 Physical Review Letters. ,vol. 78, pp. 2337- 2340 ,(1997) , 10.1103/PHYSREVLETT.78.2337
D.J. van den Heuvel, I.Y. Chan, E.J.J. Groenen, J. Schmidt, G. Meijer, Phosphorescence of C60 at 1.2 K Chemical Physics Letters. ,vol. 231, pp. 111- 118 ,(1994) , 10.1016/0009-2614(94)01223-7
M. A. Duncan, T. G. Dietz, M. G. Liverman, R. E. Smalley, Photoionization measurement of the triplet lifetime of benzene The Journal of Physical Chemistry. ,vol. 85, pp. 7- 9 ,(1981) , 10.1021/J150601A003
Ofer Sneh, Dana Dünn‐Kittenplon, Ori Cheshnovsky, The decay of triplet pyrazine in supersonic jets Journal of Chemical Physics. ,vol. 91, pp. 7331- 7339 ,(1989) , 10.1063/1.457306
Abha Sur, Philip M. Johnson, Radiationless transitions in gas phase phenol and the effects of hydrogen bonding The Journal of Chemical Physics. ,vol. 84, pp. 1206- 1209 ,(1986) , 10.1063/1.450512
Michael R. Wasielewski, Michael P. O'Neil, Keith R. Lykke, Michael J. Pellin, Dieter M. Gruen, Triplet states of fullerenes C60 and C70 : electron paramagnetic resonance spectra, photophysics, and electronic structures Journal of the American Chemical Society. ,vol. 113, pp. 2774- 2776 ,(1991) , 10.1021/JA00007A074