Au(III)-aryl intermediates in oxidant-free C–N and C–O cross-coupling catalysis
作者： Jordi Serra , Teodor Parella , Xavi Ribas
DOI: 10.1039/C6SC03699F
关键词: Catalysis 、 Cationic polymerization 、 Chemistry 、 Nucleophile 、 Photochemistry 、 Polymer chemistry 、 Reactive intermediate 、 Crystal structure 、 Aryl 、 Chemical reaction 、 Coupling
摘要: Au(III)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C–O and C–N cross coupling catalysis. The crystal structures of cyclometalated neutral cationic Au(III) are described their key role 2 electron-redox Au(I)/Au(III) catalysis couplings is shown. Nucleophiles compatible with Au-catalyzed include aromatic aliphatic alcohols amines, well water amides.
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