Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands.
作者： Sergiy Smola and Oleksandr Rogovtsov Oleksandra Berezhnytska , Irina Savchenko , Nadiya Ivakha , Olena Trunova , Nataliya Rusakova
DOI: 10.1186/S11671-017-2074-0
关键词: Chelation 、 Polymerization 、 Polymer 、 Materials science 、 Neodymium 、 Luminescence 、 Copolymer 、 Polymer chemistry 、 Organic chemistry 、 Styrene 、 Nanochemistry
摘要: The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. polycomplexes on their basis copolymers styrene N-vinylcarbazole in ratio 5:95 obtained by free-radical polymerization. results of above studies have shown that the configuration chelate unit is unchanged during As a result, type coordination was determined structure polyhedra assumed. luminescence spectra metallocomplexes polymers solutions solid state are investigated analyzed.
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