Hot Corrosion of (Sm1−xYbx)2Zr2O7 (x=0, 0.5, 1.0) Ceramics Against V2O5 Molten Salt in Air at 800°C

作者: Sa Li , Zhan-Guo Liu , Jia-Hu Ouyang

DOI: 10.1111/J.1744-7402.2011.02623.X

关键词: Molten saltMetallurgyMaterials scienceCalcinationCorrosionCeramicSialonPhase diagram

摘要: (Sm1−xYbx)2Zr2O7 (x=0, 0.5, 1.0) powders synthesized by chemical-coprecipitation and calcination method were pressureless-sintered at 1700°C for 10 h in air. Molten V2O5 reacts with to form m-ZrO2 rare-earth vanadates 800°C. The thickness of corrosion scales was investigated evaluate the hot resistance (Sm1−xYbx)2Zr2O7. against molten increases increasing Yb content. mechanisms proposed based on phase diagrams difference discussed terms basicity ceramics.

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