Electrocatalytic and morphological effects of antimony adsorbates on deposition of gold

作者: Dj Davidović , RR Adzić , None

DOI: 10.1016/0013-4686(88)80039-2

关键词: AntimonyNucleationAdsorptionDeposition (chemistry)CatalysisChemistryInorganic chemistryElectrochemistryGeneral Chemical Engineering

摘要: The electrodeposition of Au was studied in the presence Sb adsorbates. Large catalytic and morphological effects were found. A deposition is shifted by 250 mV to more positive potentials. nucleation changes from instantaneous absence Sb, into a progressive one its presence. have been explained influence on adsorption CN−-containing species, which suppresses selfinhibition this reaction. It has clearly shown that adatoms cannot play role sites, proposed earlier as cause effects. No evidence incorporation deposit

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