C−H Bond Amination from a Ferrous Dipyrromethene Complex
作者： Evan R. King , Theodore A. Betley
DOI: 10.1021/IC900219B
关键词: Azide 、 Atom 、 Ferrous 、 Intramolecular force 、 Chemistry 、 C h bond 、 Amination 、 Photochemistry
摘要: In this Communication, we report an intramolecular C−H bond amination reaction of a dipyrromethene ferrous complex with organic azides. Monitoring the spectral changes (variable-temperature NMR and UV−vis) FeII reveals no buildup intermediate during conversion starting material into nitrene-inserted product. The rate-determining step appears to be azide addition 14-electron complex, hinting at potential that these related platforms may have effect atom- group-transfer processes.
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