Recent Advances in C-O Bond Construction via C-H Activation

作者: Quan Zheng , Jie Chen , Guo-Wu Rao

DOI: 10.1134/S1070428019040249

关键词: Combinatorial chemistryYield (chemistry)ChemistryOrganic synthesisActivation methodBondFunctional groupCatalysisReaction conditionsOrganic chemistry

摘要: The direct construction of C-O bond by C-H activation is a highly efficient and practical method for the synthesis esters, ethers, hydroxy compounds. As compared to conventional mutual functional group conversion, provides not only improved atomic economy reduced number synthetic steps but also greatly overall yield multistep syntheses. Studies construct bonds are crucial in field organic catalysis research, they have already been one research hotspots related fields. According current trends development activation, different reaction types conditions classified this review, latest advances form discussed.

参考文章(52)
Tomoaki Yamaguchi, Eiji Yamaguchi, Norihiro Tada, Akichika Itoh, Direct ortho‐Hydroxylation of 2‐Phenylpyridines using Palladium(II) Chloride and Hydrogen Peroxide Advanced Synthesis & Catalysis. ,vol. 357, pp. 2017- 2021 ,(2015) , 10.1002/ADSC.201500061
Duo Zhang, Xiuling Cui, Fangfang Yang, Qianqian Zhang, Yu Zhu, Yangjie Wu, Palladium-catalyzed direct ortho C–O bond construction of azoxybenzenes with carboxylic acids and alcohols Organic chemistry frontiers. ,vol. 2, pp. 951- 955 ,(2015) , 10.1039/C5QO00120J
Zhengkai Chen, Binjie Wang, Jitan Zhang, Wenlong Yu, Zhanxiang Liu, Yuhong Zhang, Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups Organic chemistry frontiers. ,vol. 2, pp. 1107- 1295 ,(2015) , 10.1039/C5QO00004A
Ayhan S. Demir, Mustafa Emrullahoglu, Manganese(III) Acetate: A Versatile Reagent in Organic Chemistry Current Organic Synthesis. ,vol. 4, pp. 321- 350 ,(2007) , 10.2174/157017907781369289
Igor B Krylov, Vera A Vil’, Alexander O Terent’ev, Cross-dehydrogenative coupling for the intermolecular C–O bond formation Beilstein Journal of Organic Chemistry. ,vol. 11, pp. 92- 146 ,(2015) , 10.3762/BJOC.11.13
Hang Shi, David J. Babinski, Tobias Ritter, Modular C–H Functionalization Cascade of Aryl Iodides Journal of the American Chemical Society. ,vol. 137, pp. 3775- 3778 ,(2015) , 10.1021/JACS.5B01082
Xun-Xiang Guo, Da-Wei Gu, Zhengxing Wu, Wanbin Zhang, Copper-catalyzed C-H functionalization reactions: efficient synthesis of heterocycles. Chemical Reviews. ,vol. 115, pp. 1622- 1651 ,(2015) , 10.1021/CR500410Y
Zhangwei Yin, Xiaoqing Jiang, Peipei Sun, Palladium-catalyzed direct ortho alkoxylation of aromatic azo compounds with alcohols. Journal of Organic Chemistry. ,vol. 78, pp. 10002- 10007 ,(2013) , 10.1021/JO401623J
Dipannita Kalyani, Melanie S. Sanford, Regioselectivity in palladium-catalyzed C-H activation/oxygenation reactions. Organic Letters. ,vol. 7, pp. 4149- 4152 ,(2005) , 10.1021/OL051486X
Allison R. Dick, Kami L. Hull, Melanie S. Sanford, A Highly Selective Catalytic Method for the Oxidative Functionalization of C−H Bonds Journal of the American Chemical Society. ,vol. 126, pp. 2300- 2301 ,(2004) , 10.1021/JA031543M