A Highly Selective Catalytic Method for the Oxidative Functionalization of C−H Bonds

作者： Allison R. Dick , Kami L. Hull , Melanie S. Sanford

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摘要: This communication describes a new and highly practical Pd(II)-catalyzed method for the regio- chemoselective oxidative functionalization of arenes alkanes. Carbon−hydrogen bonds substrates that contain variety directing groups (e.g., pyridine, azobenzene, pyrazole, imine derivatives) are selectively transformed into esters, ethers, aryl-halides under mild conditions. The scope this reaction in terms substrate, group, oxidant is described, preliminary catalytic cycle proposed.