Potentiodynamic studies on anodic dissolution and passivation of tin, indium and tin–indium alloys in some fruit acids solutions
作者： Abdel-Rahman El-Sayed , Hossnia S. Mohran , Hany M. Abd El-Lateef
DOI: 10.1016/J.CORSCI.2009.06.050
关键词: Passivation 、 Scanning electron microscope 、 Indium 、 Corrosion 、 Dissolution 、 Citric acid 、 Inorganic chemistry 、 Electrode 、 Tin 、 Materials science
摘要: Abstract The anodic dissolution and passivation of tin, indium tin–indium alloys were studied in 0.5 M solutions both malic citric acids, using potentiodynamic technique characterized by X-ray diffraction (XRD) scanning electron microscopy (SEM). E / I curves showed that the behavior all investigated electrodes exhibits active/passive transition. active region tin involves two peaks (I II) prior to passive while one peak acid. These correspond formation InOOH In(OH) 3 /In 2 O system, respectively, but observed acid is InOOH. for ( , II III ) (I) shoulders (II). This shoulder predominates with increasing temperature due little In its at higher temperatures. disappearance this IV V high percent may be large amounts oxides on surface.
elsevier.com
sci-hub.se 参考文章(25)
A. El Sayed, S. S. Abd El Rehim, H. Mansour, Electrochemical behaviour of an indium electrode in concentrated KOH solutions at different temperatures Monatshefte Fur Chemie. ,vol. 122, pp. 1019- 1027 ,(1991) , 10.1007/BF00811110
C. M. V. B. Almeida, T. Rabóczkay, B. F. Giannetti, Inhibiting effect of citric acid on the pitting corrosion of tin Journal of Applied Electrochemistry. ,vol. 29, pp. 123- 128 ,(1999) , 10.1023/A:1003468731553
Hossnia S. Mohran, Abdel-Rahman El-Sayed, Hany M. Abd El-Lateef, Hydrogen evolution reaction on Sn, In, and Sn–In alloys in carboxylic acids Journal of Solid State Electrochemistry. ,vol. 13, pp. 1147- 1155 ,(2009) , 10.1007/S10008-008-0656-6
B.F. Giannetti, P.T.A. Sumodjo, T. Rabockai, A.M. Souza, J. Barboza, Electrochemical dissolution and passivation of tin in citric acid solution using electron microscopy techniques Electrochimica Acta. ,vol. 37, pp. 143- 148 ,(1992) , 10.1016/0013-4686(92)80023-F
Chunfen Han, Qi Liu, Douglas G. Ivey, Kinetics of Sn electrodeposition from Sn(II)–citrate solutions Electrochimica Acta. ,vol. 53, pp. 8332- 8340 ,(2008) , 10.1016/J.ELECTACTA.2008.06.037
C.M.V.B. Almeida, B.F. Giannetti, Protective film growth on tin in perchlorate and citric acid electrolytes Materials Chemistry and Physics. ,vol. 69, pp. 261- 266 ,(2001) , 10.1016/S0254-0584(00)00458-2
Bill X Huang, Pete Tornatore, Ying-Sing Li, IR and Raman spectroelectrochemical studies of corrosion films on tin Electrochimica Acta. ,vol. 46, pp. 671- 679 ,(2001) , 10.1016/S0013-4686(00)00660-5
Loïc Perring, Marija Basic-Dvorzak, Determination of total tin in canned food using inductively coupled plasma atomic emission spectroscopy. Analytical and Bioanalytical Chemistry. ,vol. 374, pp. 235- 243 ,(2002) , 10.1007/S00216-002-1420-X
Yoshiki Mino, Determination of Tin in Canned Foods by X-Ray Fluorescence Spectrometry Journal of Health Science. ,vol. 52, pp. 67- 72 ,(2006) , 10.1248/JHS.52.67
A.S. Tselesh, Anodic behaviour of tin in citrate solutions: The IR and XPS study on the composition of the passive layer Thin Solid Films. ,vol. 516, pp. 6253- 6260 ,(2008) , 10.1016/J.TSF.2007.11.118