Methane decomposition over Pd promoted Ni/MgAl 2 O 4 catalysts for the production of COx free hydrogen and multiwalled carbon nanotubes
作者： Manoj Pudukudy , Zahira Yaakob , Mohd Sobri Takriff
DOI: 10.1016/J.APSUSC.2015.08.246
关键词: Non-blocking I/O 、 Inorganic chemistry 、 Catalyst support 、 Palladium 、 Catalysis 、 Materials science 、 Carbon nanotube 、 Thermal decomposition 、 Hydrogen 、 Methane
摘要: Abstract This article reports the synthesis, characterization and catalytic performance of Pd promoted Ni/MgAl 2 O 4 spinel catalysts for thermal decomposition methane into hydrogen carbon nanotubes. The as-synthesized were characterized their structural, textural, morphological properties. properties catalyst found to be enhanced with promoter. It effectively increased surface area without affecting pore parameters improved fine dispersion NiO particles on magnesium aluminate. reduction temperature was lowered after deposition. Moreover, provided high activity stability decomposition. A maximum yield ∼57% obtained over at a reaction 700 °C any deactivation 420 min time stream. Moreover highly uniform, interwoven thin multi-walled nanotubes graphitization degree deposited catalysts.
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Manoj Pudukudy, Zahira Yaakob, Zubair Shamsul Akmal, Direct decomposition of methane over Pd promoted Ni/SBA-15 catalysts Applied Surface Science. ,vol. 353, pp. 127- 136 ,(2015) , 10.1016/J.APSUSC.2015.06.073
I Suelves, JL Pinilla, MJ Lázaro, R Moliner, JM Palacios, None, Effects of reaction conditions on hydrogen production and carbon nanofiber properties generated by methane decomposition in a fixed bed reactor using a NiCuAl catalyst Journal of Power Sources. ,vol. 192, pp. 35- 42 ,(2009) , 10.1016/J.JPOWSOUR.2008.11.096
Manoj Pudukudy, Zahira Yaakob, Methane decomposition over Ni, Co and Fe based monometallic catalysts supported on sol gel derived SiO2 microflakes Chemical Engineering Journal. ,vol. 262, pp. 1009- 1021 ,(2015) , 10.1016/J.CEJ.2014.10.077
Giselle B Nuernberg, Edson L Foletto, Luiz FD Probst, Neftalí LV Carreño, Marcelo A Moreira, None, MgAl2O4 spinel particles prepared by metal–chitosan complexation route and used as catalyst support for direct decomposition of methane Journal of Molecular Catalysis A-chemical. ,vol. 370, pp. 22- 27 ,(2013) , 10.1016/J.MOLCATA.2012.12.007
Hazzim F. Abbas, W.M.A. Wan Daud, Hydrogen production by methane decomposition: A review International Journal of Hydrogen Energy. ,vol. 35, pp. 1160- 1190 ,(2010) , 10.1016/J.IJHYDENE.2009.11.036
A.E. Awadallah, A.A. Aboul-Enein, D.S. El-Desouki, A.K. Aboul-Gheit, Catalytic thermal decomposition of methane to COx-free hydrogen and carbon nanotubes over MgO supported bimetallic group VIII catalysts Applied Surface Science. ,vol. 296, pp. 100- 107 ,(2014) , 10.1016/J.APSUSC.2014.01.055
J. Sarada Prasad, Vivek Dhand, V. Himabindu, Y. Anjaneyulu, Pawan Kumar Jain, Balaji Padya, Production of hydrogen and carbon nanofibers through the decomposition of methane over activated carbon supported Pd catalysts International Journal of Hydrogen Energy. ,vol. 35, pp. 10977- 10983 ,(2010) , 10.1016/J.IJHYDENE.2010.07.021
Ji-Guang Li, Takayasu Ikegami, Jong-Heun Lee, Toshiyuki Mori, Yoshiyuki Yajima, A wet-chemical process yielding reactive magnesium aluminate spinel (MgAl2O4) powder Ceramics International. ,vol. 27, pp. 481- 489 ,(2001) , 10.1016/S0272-8842(00)00107-3
Beatriz Zapata, Miguel A. Valenzuela, Jorge Palacios, Enelio Torres-Garcia, Effect of Ca, Ce or K oxide addition on the activity of Ni/SiO2 catalysts for the methane decomposition reaction International Journal of Hydrogen Energy. ,vol. 35, pp. 12091- 12097 ,(2010) , 10.1016/J.IJHYDENE.2009.09.072
Natalia P. Ivleva, Armin Messerer, Xin Yang, Reinhard Niessner, Ulrich Pöschl, Raman microspectroscopic analysis of changes in the chemical structure and reactivity of soot in a diesel exhaust aftertreatment model system. Environmental Science & Technology. ,vol. 41, pp. 3702- 3707 ,(2007) , 10.1021/ES0612448