作者: S. J. Benkovic , K. J. Schray
DOI: 10.1007/978-1-4684-9978-0_13
关键词: Phosphonium salt 、 Alkaline hydrolysis (body disposal) 、 Acetyl phosphate 、 Chemistry 、 Catalysis 、 Transition state 、 Phenyl phosphate 、 Combinatorial chemistry 、 Mechanism (sociology)
摘要: Our intent in this chapter is to present an abbreviated but inclusive description of the probable transition states involved phosphoryl-transfer reactions as elucidated by physical organic studies. A number critical, extensive reviews on particular aspects topic have recently appeared.(1–9) Probable modes catalysis will be delineated particularly relation their anticipated involvement biological phosphoryl transfer.