Electromechanical Properties of PVDF-Based Polymers Reinforced with Nanocarbonaceous Fillers for Pressure Sensing Applications.
作者： Javier Vicente , P. Costa , S. Lanceros-Mendez , Jose Manuel Abete , Aitzol Iturrospe
DOI: 10.3390/MA12213545
关键词: Filler (packaging) 、 Nanocomposite 、 Polymer 、 Materials science 、 Composite material 、 Carbon nanotube 、 Piezoresistive effect 、 Oxide 、 Percolation threshold 、 Graphene
摘要: Polymer-based composites reinforced with nanocarbonaceous materials can be tailored for functional applications. Poly(vinylidene fluoride) (PVDF) carbon nanotubes (CNT) or graphene different filler contents have been developed as potential piezoresistive materials. The mechanical properties of the nanocomposites depend on PVDF matrix, type, and content. 6010 is a relatively more ductile material, whereas PVDF-HFP (hexafluropropylene) shows larger maximum strain near 300% CNT, 10 times higher than pristine polymer. This behavior similar all CNT. On other hand, reduced oxide (rGO)/PVDF decrease compared to neat PVDF. It shown that use copolymers does not influence electrical composites. CNT leads percolation threshold around 0.5 wt.%, rGO show at ≈ 2 wt.%. Both present excellent linearity between applied pressure resistance variation, sensibility (PS) decreasing pressure, from PS 1.1 0.2 MPa−1. A proof concept demonstration presented, showing suitability industrial sensing
mdpi.com
harvard.edu
mondragon.edu参考文章(59)
Junwei Gu, Xutong Yang, Zhaoyuan Lv, Nan Li, Chaobo Liang, Qiuyu Zhang, Functionalized graphite nanoplatelets/epoxy resin nanocomposites with high thermal conductivity International Journal of Heat and Mass Transfer. ,vol. 92, pp. 15- 22 ,(2016) , 10.1016/J.IJHEATMASSTRANSFER.2015.08.081
D. Lange, P.Roca i Cabarrocas, N. Triantafyllidis, D. Daineka, Piezoresistivity of thin film semiconductors with application to thin film silicon solar cells Solar Energy Materials and Solar Cells. ,vol. 145, pp. 93- 103 ,(2016) , 10.1016/J.SOLMAT.2015.09.014
S. F. Mendes, C. M. Costa, C. Caparros, V. Sencadas, S. Lanceros-Méndez, Effect of filler size and concentration on the structure and properties of poly(vinylidene fluoride)/BaTiO3 nanocomposites Journal of Materials Science. ,vol. 47, pp. 1378- 1388 ,(2012) , 10.1007/S10853-011-5916-7
Francesco Marotti de Sciarra, On non-local and non-homogeneous elastic continua International Journal of Solids and Structures. ,vol. 46, pp. 651- 676 ,(2009) , 10.1016/J.IJSOLSTR.2008.09.018
S. Lanceros-Méndez, P. Costa, A. Ferreira, V. Sencadas, J.C. Viana, Electro-mechanical properties of triblock copolymer styrene-butadiene-styrene / carbon nanotube composites for large deformation sensor applications Sensors and Actuators A-physical. ,vol. 201, pp. 458- 467 ,(2013) , 10.1016/J.SNA.2013.08.007
Jong-Il Weon, Mechanical and thermal behavior of polyamide-6/clay nanocomposite using continuum-based micromechanical modeling Macromolecular Research. ,vol. 17, pp. 797- 806 ,(2009) , 10.1007/BF03218617
G. Georgousis, C. Pandis, A. Kalamiotis, P. Georgiopoulos, A. Kyritsis, E. Kontou, P. Pissis, M. Micusik, K. Czanikova, J. Kulicek, M. Omastova, Strain sensing in polymer/carbon nanotube composites by electrical resistance measurement Composites Part B: Engineering. ,vol. 68, pp. 162- 169 ,(2015) , 10.1016/J.COMPOSITESB.2014.08.027
Jonathan N. Coleman, Umar Khan, Werner J. Blau, Yurii K. Gun’ko, Small but strong: A review of the mechanical properties of carbon nanotube–polymer composites Carbon. ,vol. 44, pp. 1624- 1652 ,(2006) , 10.1016/J.CARBON.2006.02.038
S. Chatterjee, F. Nafezarefi, N.H. Tai, L. Schlagenhauf, F.A. Nüesch, B.T.T. Chu, Size and synergy effects of nanofiller hybrids including graphene nanoplatelets and carbon nanotubes in mechanical properties of epoxy composites Carbon. ,vol. 50, pp. 5380- 5386 ,(2012) , 10.1016/J.CARBON.2012.07.021
Basudam Adhikari, Sarmishtha Majumdar, Polymers in sensor applications Progress in Polymer Science. ,vol. 29, pp. 699- 766 ,(2004) , 10.1016/J.PROGPOLYMSCI.2004.03.002