作者: Judit Canadell , Han Goossens , Bert Klumperman
DOI: 10.1021/MA2001492
关键词: Vitrimers 、 Moderate temperature 、 Self-healing 、 Synthetic materials 、 Self-healing material 、 Polymer 、 Disulfide bond 、 Nanotechnology 、 Chemistry 、 Full recovery
摘要: Autonomous healing of damage is a common phenomenon in living organisms but hardly ever encountered synthetic materials. Disulfide chemistry used to introduce self-healing ability covalently cross-linked rubber. cut takes place at moderate temperatures and leads full recovery mechanical properties. This result achieved by introducing disulfide groups the network that are able exchange, leading renewal cross-links across damaged surfaces. The process can be repeated many times. combination their unique properties applicability for large variety polymers makes this approach ideal coatings.