Diastereoisomer separation and absolute configuration of (methylsorbate)Fe(CO)2L, (sorbaldehyde)Fe(CO)2L and (1-methoxycyclohexadiene)Fe(CO)2L (L = (+)-neomenthyl(PPh2)]
作者： James A.S. Howell , Marie C. Tirvengadum , Adrian D. Squibb , Garry Walton , Patrick McArdle
DOI: 10.1016/0022-328X(88)80287-0
关键词: Absolute configuration 、 Inorganic compound 、 Stereochemistry 、 Circular dichroism 、 Chemistry 、 Molecule 、 Crystal structure 、 Diastereomer 、 Crystallography
摘要: Abstract Substitution of CO in (methylsorbate)-, (sorbaldehyde)- and (1-methoxycyclohexadiene)-Fe(CO)2L by (+)-(neomenthyl)PPh2 allows facile diastereoisomer separation. The absolute configurations have been established X-ray crystallography circular dichroism spectroscopy.
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