Phosphine-centred resolution of (η4-diene)Fe(CO)3 complexes: (η4-tropone)Fe(CO)2L and (η4-isoprene)Fe(CO)2L [L = (+)-(neomenthyl)PPh2]
作者： James A.S. Howell , Adrian D. Squibb , Garry Walton , Patrick McArdle , Desmond Cunningham
DOI: 10.1016/S0022-328X(00)99616-5
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摘要: Abstract (η 4 -Tropone)Fe(CO) 3 and -isoprene)Fe(CO) form separable diastereoisomers on substitution of CO by (+)-(neomenthyl)PPh 2 . In the tropone complex, diastereoisomer interconversion occurs a 1,3-metal shift. The absolute configuration isoprene complex has been determined crystallographically.
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