Pore structure of bulk tungsten carbide powder catalysts

作者: A. L�fberg , L. Seyfried , P. Blehen , S. Decker , J. M. Bastin

DOI: 10.1007/BF00817056

关键词: ChemistryTungsten carbideInorganic chemistryTungsten trioxideAdsorptionCatalysisMicroporous materialPorosityHeterogeneous catalysisIndustrial catalysts

摘要: Bulk tungsten carbide catalysts are prepared by direct carburization/reduction of trioxide in methane-hydrogen mixtures. The catalytic properties such have been studied several authors. porous structure these is adsorption N2, Kr, CF4 and neohexane. Adsorption isotherms hysteresis loops for the suggest presence a microporous made parallel plates distant approximately 20 A. These results compared to those obtained using hydrogen oxidation where condensation was observed.

参考文章(10)
R. B. Levy, M. Boudart, Platinum-Like Behavior of Tungsten Carbide in Surface Catalysis Science. ,vol. 181, pp. 547- 549 ,(1973) , 10.1126/SCIENCE.181.4099.547
Sidney John Gregg, Adsorption, Surface Area and Porosity ,(1967)
Enrique Iglesia, Joseph E Baumgartner, Fabio H Ribeiro, Michel Boudart, Bifunctional reactions of alkanes on tungsten carbides modified by chemisorbed oxygen Journal of Catalysis. ,vol. 131, pp. 523- 544 ,(1991) , 10.1016/0021-9517(91)90284-B
Jeong-Gil Choi, James R. Brenner, Craig W. Colling, Brain G. Demczyk, Judy L. Dunning, Levi T. Thompson, Synthesis and characterization of molybdenum nitride hydrodenitrogenation catalysts Catalysis Today. ,vol. 15, pp. 201- 222 ,(1992) , 10.1016/0920-5861(92)80176-N
Enrique Iglesia, Fabio H. Ribeiro, Michel Boudart, Joseph E. Baumgartner, Synthesis, characterization, and catalytic properties of clean and oxygen-modified tungsten carbides Catalysis Today. ,vol. 15, pp. 307- 337 ,(1992) , 10.1016/0920-5861(92)80181-L
Fabio H Ribeiro, Ralph A Dalla Betta, Michel Boudart, Joseph Baumgartner, Enrique Iglesia, Reactions of neopentane, methylcyclohexane, and 3,3-dimethylpentane on tungsten carbides: The effect of surface oxygen on reaction pathways Journal of Catalysis. ,vol. 130, pp. 86- 105 ,(1991) , 10.1016/0021-9517(91)90094-K
G. Bronoel, E. Museux, G. Leclercq, L. Leclercq, N. Tassin, Study of hydrogen oxidation on carbides Electrochimica Acta. ,vol. 36, pp. 1543- 1547 ,(1991) , 10.1016/0013-4686(91)85004-Q
Jae Hoon Lee, Charles E. Hamrin, Burtron H. Davis, Catalytic conversion of alcohols and amines using metal nitride catalysts Catalysis Today. ,vol. 15, pp. 223- 241 ,(1992) , 10.1016/0920-5861(92)80177-O