Basische metalle
作者： H Werner , S Lotz , B Heiser
DOI: 10.1016/S0022-328X(00)83022-3
关键词: Medicinal chemistry 、 Cationic polymerization 、 Yield (chemistry) 、 Isomerization 、 ASPH 、 Compound c 、 Chemistry
摘要: Abstract The reaction of C 5 H Rh(PMe 3 )C 2 4 or )CO with CH I affords the compound RhCH I(PMe )I from which stable cationic ylide-rhodium complexes [C L(PMe )I]X (L = PPh , PPr i AsPh SMe NEt ; X I, PF 6 ) are prepared. In presence also undergoes isomerisation to yield Rh(CH PMe . reacts NaOMe and NaSMe give OMe(PMe SMe(PMe )SMe, respectively.
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