Photochemisch induzierte oxidative addition von dichlormethan an einen platin(0)-komplex
作者： O.J. Scherer , H. Jungmann
DOI: 10.1016/S0022-328X(00)82670-4
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摘要: Abstract Photoinduced oxidative addition of the solvent CH 2 Cl to (Ph 3 P) Pt(C H 4 ) with formation cis/trans -(Ph PtCl(CH Cl) and cis -Cl Pt(PPh is observed over several days at ambient temperature. In presence double ylide (R Si) NP( NSiR , R this reaction occurs even in dark. Sunlight or irradiation a 500 W lamp increases, whereas duroquinone decreases, rate reaction. This indicates that, least natural light (wavelength > 290 nm), free radicals involved.
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