Darstellung und eigenschaften von und reaktionen mit metallhaltigen heterocyclen: XXV. Synthese und eigenschaften neuer platina- und rhodacycloalkane durch substitution und oxidative addition einer CCl-bindung
作者： Ekkehard Lindner , Faouzi Bouachir , Riad Fawzi , Dieter Hubner
DOI: 10.1016/S0022-328X(00)96088-1
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摘要: The platinacyclopentane derivative [Cl(CH2)3R2P](Cl)PtPR2CH2CH2CH2 is formed by action of Cl(CH2)3PR2 on Pt(COD)2 in n-hexane via the not isolable Pt[PR2(CH2)3Cl]2 (R C6H11) oxidative addition a CCl bond to platinum. [μ-CIRh(CO)2]2 reacts benzene with under partially CO substitution give stable intermediate Cl(OC)Rh[PR2(CH2)3Cl]2. In boiling toluene rhodium occurs formation phospharhodacyclopentane [CI(CH2)3R2P] Cl2(OC)-RhPR2CH2CH2CH2 C6H5). 31P{1H}-NMR spectra compound characterized an ABX system, that platinum superposition pattern AB spectrum.
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sci-hub.se 参考文章(28)
Ekkehard Lindner, Guido Funk, Darstellung und eigenschaften von und reaktionen mit metallhaltigen heterocyclen Journal of Organometallic Chemistry. ,vol. 216, pp. 393- 402 ,(1981) , 10.1016/S0022-328X(00)85820-9
R. J. McKinney, G. Firestein, Herbert D. Kaesz, Metalation reaction. VII. Metalation of aromatic ketones and anthraquinone with methylmanganese and methylrhenium carbonyl complexes Inorganic Chemistry. ,vol. 14, pp. 2057- 2061 ,(1975) , 10.1021/IC50151A008
S. Hietkamp, D.J. Stufkens, K. Vrieze, Activation of CH bonds by transition metals I. Metallation of allylphosphines coordinated to iridium(I) Journal of Organometallic Chemistry. ,vol. 122, pp. 419- 428 ,(1976) , 10.1016/S0022-328X(00)82403-1
Philip E. Garrou, .DELTA.R-ring contributions to phosphorus-31 NMR parameters of transition-metal-phosphorus chelate complexes Chemical Reviews. ,vol. 81, pp. 229- 266 ,(1981) , 10.1021/CR00043A002
O.J. Scherer, H. Jungmann, Photochemisch induzierte oxidative addition von dichlormethan an einen platin(0)-komplex Journal of Organometallic Chemistry. ,vol. 208, pp. 153- 159 ,(1981) , 10.1016/S0022-328X(00)82670-4
Ram G. Goel, Reynaldo. Montemayor, Reactions of tri-tert-butylphosphine with platinum(II) and palladium(II). Facile intramolecular metalation of tri-tert-butylphosphine Inorganic Chemistry. ,vol. 16, pp. 2183- 2186 ,(1977) , 10.1021/IC50175A007
Ekkekard Lindner, Guido Funk, Sigurd Hoehne, Darstellung und Eigenschaften von und Reaktionen mit metallhaltigen Heterocyclen, XIII. Darstellung und Kristallstrukturen neuartiger Mangana- und Rhenaphosphacycloalkane durch Substitution und reduktive Cycloeliminierung mit ω-Chlor-1-(diphenylphosphino)alkanen Chemische Berichte. ,vol. 114, pp. 2465- 2478 ,(1981) , 10.1002/CBER.19811140713
Petr Jandik, Ulrich Schubert, Hubert Schmidbaur, Methylene Bridging of two Gold Atoms through Double Oxidative Addition of Methylene Dihalides to a Cyclic Ylide Complex Angewandte Chemie. ,vol. 21, pp. 73- 73 ,(1982) , 10.1002/ANIE.198200731
W. Fahrion, Die Fettanalyse im Jahre 1902 Zeitschrift für Angewandte Chemie. ,vol. 16, pp. 73- 85 ,(1903) , 10.1002/ANGE.19030160402
Jean Dehand, Christine Mutet, Michel Pfeffer, Reactivite d'anilines tertiaires vis-a-vis de complexes du palladium: dealkylation de l'azote et cyclopalladation Journal of Organometallic Chemistry. ,vol. 209, pp. 255- 270 ,(1981) , 10.1016/S0022-328X(00)93596-4